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Magnesium citrate and potassium citrate solution is a combination medication used to prevent and treat certain types of kidney stones. Magnesium Citrate: Magnesium citrate helps to inhibit the formation of kidney stones by binding with oxalate, a substance that contributes to the formation of calcium oxalate stones. By reducing oxalate levels in the urine, magnesium citrate helps to prevent the formation of these types of kidney stones. Potassium Citrate: Potassium citrate works by increasing the pH of urine, making it less acidic. This helps to prevent the formation of uric acid and cystine stones, as these types of stones tend to form in acidic urine environments. Additionally, potassium citrate can help dissolve existing uric acid stones by alkalinizing the urine.